Process Equipment and Plant Design
Pick out the wrong statement pertaining to 'Horton sphere' used for the storage of liquid ammonia.

Horton sphere is used for the storage of gases and volatile liquid at a moderate pressure of 1 to 10 kg/cm²
Horton sphere is used for the storage of liquid at sub-zero temperature at very high pressure upto 200 kg/cm²
Thickness of spherical shell is half that of the cylinderical vessel under same operating pressure condition. Besides, the ratio of surface area to volume is less for sphere than any other shape ; hen
Diameter of Horton sphere is normally 6 to 25 metres and it is supported by 6 to 12 nos. tubular or rolled section column

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Process Equipment and Plant Design
Ponchon Savarit method is based on the use of enthalpy concentration diagram, which contains the bubble point curve (saturated liquid curve), dew point curve (saturated vapour curve) and equilibrium tie lines. As compared to McCabe-Thiele's method, this method

All of these
Is more accurate in finding the number of equilibrium stages
Facilitates direct calculation of heat load on reboiler & condenser from, the diagram used in this method
Accounts for the enthalpy changes in the process

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