Mass Transfer
McCabe-Thiele method of binary distillation does not assume that the

Sensible heat changes are negligible compared with latent heat changes
Molar latent heats of all components are equal
Heat of mixing is negligible
None of these

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Mass Transfer
Entrainer used in azeotropic distillation should

Have high latent heat of vaporisation
Form a new azeotrope of low relative volatility with one of the constituents of the mixture
Form a low boiling azeotrope with one of the constituents of the mixture
Have high viscosity to provide high tray efficiency

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