Mass Transfer
McCabe-Thiele method of binary distillation does not assume that the

Heat of mixing is negligible
Sensible heat changes are negligible compared with latent heat changes
Molar latent heats of all components are equal
None of these

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Mass Transfer
When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of

Vapour pressure of component A to the total pressure
Vapour pressure of component A to that of component B
Vapour pressure of component A to the partial pressure of A
Partial pressure of component A to the total pressure

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