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CHEMICAL ENGINEERING THERMODYNAMICS

Chemical Engineering Thermodynamics
Degree of freedom of a system consisting of a gaseous mixture of H₂ and NH₃ will be

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3
2
1

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Chemical Engineering Thermodynamics
A closed system is cooled reversibly from 100°C to 50°C. If no work is done on the system

U is constant but S decreases
Its internal energy (U) decreases and its entropy (S) increases
U decreases but S is constant
U and S both decreases

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Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = - nR ln (P₂/P₁), holds good for

Cooling of a real gas
Expansion of a real gas
Reversible isothermal volume change
Heating of an ideal gas

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Chemical Engineering Thermodynamics
For any system, what is the minimum number of degrees of freedom?

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3

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Chemical Engineering Thermodynamics
Which of the following is not a unit of the equilibrium constant Kp? (where, Δx = number of moles of products number of moles of reactants)

(atm)Δx, when Δx is positive
(atm)Δx2, when Δx > 0
(atm)Δx, when Δx is negative
Dimensionless, when Δx = 0

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