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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For any system, what is the minimum number of degrees of freedom?

2
1
3
0

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂V/∂S)P = (∂T/∂P)S
(∂S/∂V)T = (∂P/∂T)V
(∂S/∂P)T = -(∂V/∂T)P
(∂T/∂V)S = -(∂P/∂S)V

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Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

0.5 RT
-RT ln 0.5
2 RT
-2 RT ln 0.5

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Chemical Engineering Thermodynamics
Joule-Thomson co-efficient for a perfect gas is

None of these
Zero
Positive
Negative

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Chemical Engineering Thermodynamics
Gibbs free energy (F) is defined as

F = H + TS
F = E + TS
F = H - TS
F = E - TS

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Chemical Engineering Thermodynamics
The enthalpy change when ammonia gas is dissolved in water is called the heat of

Solution
Combustion
Dilution
Formation

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