Chemical Engineering Thermodynamics
A closed system is cooled reversibly from 100°C to 50°C. If no work is done on the system

U and S both decreases
U decreases but S is constant
Its internal energy (U) decreases and its entropy (S) increases
U is constant but S decreases

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Chemical Engineering Thermodynamics
Gibbs-Duhem equation

Applies only to binary systems
States that n₁dμ₁ + n₂dμ₂ + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
None of these
Finds no application in gas-liquid equilibria involved in distillation

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