Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = - nR ln (P₂/P₁), holds good for

Expansion of a real gas
Reversible isothermal volume change
Cooling of a real gas
Heating of an ideal gas

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Chemical Engineering Thermodynamics
In the reaction, H₂ +I₂ ⇋ 2HI, addition of an inert gas will

Not effect the equilibrium conditions
Increase the partial pressure of H₂
Increase the partial pressure of I₂
Increase the total pressure and hence shift the equilibrium towards the right

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