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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Pick out the correct equation relating 'F' and 'A'.

F = A - TS
F = A + PV
F = E + A
F = A + TS

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂P)T = -(∂V/∂T)P
(∂S/∂V)T = (∂P/∂T)V

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Chemical Engineering Thermodynamics
Near their critical temperatures, all gases occupy volumes __________ that of the ideal gas.

Half
More than
Same as
Less than

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Chemical Engineering Thermodynamics
1st law of thermodynamics is nothing but the law of conservation of

None of these
Momentum
Energy
Mass

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Chemical Engineering Thermodynamics
In an adiabatic process, the

Temperature change is zero
Enthalpy remains constant
Work done is a path function
Heat transfer is zero

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Chemical Engineering Thermodynamics
The reaction A (l) R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The number of degrees of freedom are

1
2
3

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