Chemical Engineering Thermodynamics
An irreversible process

Yields an amount of work less than that of a reversible process
Is an idealised visualisation of behaviour of a system
Is the analog of linear frictionless motion in machines
Yields the maximum amount of work

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Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

All of these
Vapour pressure is relatively low and the temperature does not vary over wide limits
Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
Volume in the liquid state is negligible compared with that in the vapour state

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