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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Clausius - Clayperon equation is applicable to __________ equilibrium processes.

All of the listed here
Liquid-vapor
Solid-vapor
Solid-liquid

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Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = - nR ln (P₂/P₁), holds good for

Cooling of a real gas
Reversible isothermal volume change
Expansion of a real gas
Heating of an ideal gas

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Chemical Engineering Thermodynamics
Which is not constant for an ideal gas?

(∂P/∂V)T
(∂P/∂V)V
(∂V/∂T)P
All of these

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Chemical Engineering Thermodynamics
In case of vapour compression refrigeration system, elevating the evaporator temperature (keeping the condenser temperature constant) results in

Enhanced COP
Decreased COP
Increased or decreased COP ; depending upon the type of refrigerant
No change in the value of COP

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Chemical Engineering Thermodynamics
In case of the decomposition of hydroiodic acid (2HI ⇋ H₂ + I₂), addition of H₂ (at equilibrium condition) will

Decrease the partial pressure of HI
Diminish the degree of dissociation of HI
None of these
Increase the partial pressure of I₂

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Chemical Engineering Thermodynamics
At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)

μ° + RT ln f
μ°+ R lnf
μ° + R/T lnf
μ° + T lnf

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