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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For a given substance at a specified temperature, activity is __________ to fugacity.

Directly proportional
Equal
None of these
Inversely proportional

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Chemical Engineering Thermodynamics
When dilute aqueous solutions of two salts are mixed, the process is associated with

No change in temperature
Increase in temperature
Decrease in temperature
Change in temperature which is a function of composition

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Chemical Engineering Thermodynamics
Third law of thermodynamics is helpful in

Calculating absolute entropies of substances at different temperature
Prediction of the extent of a chemical reaction
Both B and C
Evaluating entropy changes of chemical reaction

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Chemical Engineering Thermodynamics
At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)

μ° + T lnf
μ°+ R lnf
μ° + R/T lnf
μ° + RT ln f

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Chemical Engineering Thermodynamics
When a gas in a vessel expands, its internal energy decreases. The process involved is

Adiabatic
Irreversible
Isothermal
Reversible

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Chemical Engineering Thermodynamics
Degree of freedom of a system consisting of a gaseous mixture of H₂ and NH₃ will be

3
1
0
2

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