Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature and pressure only
Temperature only
Temperature, pressure and liquid composition xi only
Temperature, pressure, liquid composition xi and vapour composition yi

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Chemical Engineering Thermodynamics
A refrigeration cycle is a reversed heat engine. Which of the following has the maximum value of the co-efficient of performance (COP) for a given refrigeration effect?

Vapor compression cycle using expansion engine
Carnot refrigeration cycle
Vapor compression cycle using expansion valve
Air refrigeration cycle

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