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CHEMICAL ENGINEERING THERMODYNAMICS

Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂V)T = (∂P/∂T)V
(∂S/∂P)T = -(∂V/∂T)P
(∂V/∂S)P = (∂T/∂P)S

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Chemical Engineering Thermodynamics
Which of the following processes can not be made reversible even under ideal condition of operation?

Free expansion of a gas
Compression of air in a compressor
All of these
Expansion of steam in a turbine

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Chemical Engineering Thermodynamics
Heat is added at constant pressure in an ideal __________ cycle.

Brayton
Rankine
Both B and C
Stirling

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Chemical Engineering Thermodynamics
Heat is added at constant temperature in an ideal __________ cycle.

Stirling
Rankine
Brayton
None of these

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Chemical Engineering Thermodynamics
The standard state of a gas (at a given temperature) is the state in which fugacity is equal to

Both A & B
Activity
Unity
Neither A nor B

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