Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂P)T = -(∂V/∂T)P
(∂S/∂V)T = (∂P/∂T)V

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Chemical Engineering Thermodynamics
Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇋ PCl3 + Cl₂.Degree of dissociation of PCl5 will

None of these
Increase on addition of an inert gas at constant pressure
Decrease on addition of Cl₂
Decrease on increasing the pressure of the system

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