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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Heat is added at constant temperature in an ideal __________ cycle.

None of these
Rankine
Stirling
Brayton

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Chemical Engineering Thermodynamics
Fugacity is most helpful in

The study of chemical equilibria involving gases at atmospheric pressure
None of these
Representing actual behaviour of real gases
Representing actual behaviour of ideal gases

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Chemical Engineering Thermodynamics
When a system is in equilibrium for all possible processes, the differential or finite change of entropy is

< 0
= 0
> 0
None of these

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Chemical Engineering Thermodynamics
The principle applied in liquefaction of gases is

Adiabatic expansion
Both A and B
Neither A nor B
Joule-Thomson effect

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Chemical Engineering Thermodynamics
Refrigeration cycle

Both A and B
Involves transfer of heat from low temperature to high temperature
Neither A nor B
Violates second law of thermodynamics

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Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

0.5 RT
-RT ln 0.5
2 RT
-2 RT ln 0.5

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