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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases.

Remains same
Decreases linearly
Increases
Decreases

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Chemical Engineering Thermodynamics
Internal energy of an ideal gas

Is independent of temperature
None of these
Increases with increase in pressure
Decreases with increase in temperature

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Chemical Engineering Thermodynamics
Which of the following behaves most closely like an ideal gas?

He
H₂
N₂
O₂

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Chemical Engineering Thermodynamics
In which of the following reaction equilibria, the value of equilibrium constant Kp will be more than is Kc?

2HI ⇋ H₂ + I₂
2SO₂ + O₂ ⇋ 2SO₃
N₂O₄ ⇋ 2NO₂
None of these

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Chemical Engineering Thermodynamics
At a given temperature, the volume of a gas dissolved in a solvent __________ with increase in pressure.

Increases
Remains unchanged
May increase or decrease; depends on the gas
Decreases

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂S/∂P)T = -(∂V/∂T)P
(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂V)T = (∂P/∂T)V
(∂V/∂S)P = (∂T/∂P)S

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