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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases.

Remains same
Decreases linearly
Decreases
Increases

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Chemical Engineering Thermodynamics
Heat of reaction at constant volume is identified with __________ change.

Enthalpy
Either A or B
Internal energy
Neither A nor B

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Chemical Engineering Thermodynamics
The amount of heat required to decompose a compound into its elements is __________ the heat of formation of that compound from its elements.

More than
Less than
Not related to
Same as

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Chemical Engineering Thermodynamics
At triple point (for one component system), vapour pressure of solid as compared to that of liquid will be

Same
More
Less
More or less ; depending on the system

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Chemical Engineering Thermodynamics
At __________ point, all the three phases (i.e.solid, liquid and gas) co-exist.

Triple
Critical
Plait
Eutcetic

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂P)T = -(∂V/∂T)P
(∂S/∂V)T = (∂P/∂T)V

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