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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
No work is done by the system, when a reaction occurs at constant

Temperature
None of these
Volume
Pressure

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Chemical Engineering Thermodynamics
Equilibrium constant decreases as the temperature

Increases, for an exothermic reaction
Increases, for an endothermic reaction
None of these
Decreases, for an exothermic reaction

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Chemical Engineering Thermodynamics
At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)

μ° + RT ln f
μ° + R/T lnf
μ°+ R lnf
μ° + T lnf

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Chemical Engineering Thermodynamics
Joule-Thomson Co-efficient at any point on the inversion curve is

-ve
+ ve
∞

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Chemical Engineering Thermodynamics
An isolated system can exchange __________ with its surroundings.

Neither matter nor energy
Energy
Matter
Both matter and energy

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Chemical Engineering Thermodynamics
For an exothremic reaction

Both ΔH and ΔE are negative
Only enthalpy change (ΔH) is negative
Only internal energy change (ΔE) is negative
Enthalpy change is zero

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