Chemical Engineering Thermodynamics
At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)

μ° + RT ln f
μ° + T lnf
μ° + R/T lnf
μ°+ R lnf

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Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

Vapour pressure is relatively low and the temperature does not vary over wide limits
Volume in the liquid state is negligible compared with that in the vapour state
Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
All of these

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