Mass Transfer
In steam distillation, the

Product must be immiscible with water
Temperature is higher than the boiling point of either component
Temperature is more than 100° C
Temperature is 100°C

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Mass Transfer
Fenske's equation for determining the minimum number of theoretical stages in distillation column holds good, when the

Multicomponent distillation is involved
Mixture (to be separated) shows positive deviation from ideality
Mixture (to be separated) shows negative deviation from ideality
Relative volatility is reasonably constant

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