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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The root mean square speed of molecules of a gas is equal to (where, m = mass of the molecule K = Boltzman's constant, T = absolute temperature)

√(6KT/m)
3KT/m
√(3KT/m)
√(2KT/m)

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Chemical Engineering Thermodynamics
With increase in temperature, the atomic heat capacities of all solid elements

Remains unchanged
Decreases
Decreases linearly
Increases

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Chemical Engineering Thermodynamics
Fugacity is most helpful in

Representing actual behaviour of real gases
None of these
The study of chemical equilibria involving gases at atmospheric pressure
Representing actual behaviour of ideal gases

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Chemical Engineering Thermodynamics
In a reversible process

Tds = dE + dW
DW - dE = Tds
Tds - dW + dE >0
DE - dW = Tds

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Chemical Engineering Thermodynamics
The accentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr⁻¹ = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of accentric factor is always

> 2
> 1
< 1
< 3

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Chemical Engineering Thermodynamics
The expression for entropy change, ΔS = n Cp . ln (T₂/T₁), is valid for the __________ of a substance.

Cooling
Both B and C
Heating
Simultaneous pressure & temperature change

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