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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The accentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr⁻¹ = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of accentric factor is always

> 2
< 1
> 1
< 3

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Chemical Engineering Thermodynamics
Internal energy of an element at 1 atm and 25° C is __________ kcal/kg.mole.

273
0
None of these
25

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂V)T = (∂P/∂T)V
(∂S/∂P)T = -(∂V/∂T)P

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Chemical Engineering Thermodynamics
Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be

Doubled
One fourth of its original value
Halved
Same

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Chemical Engineering Thermodynamics
Co-efficient of performance for a reversed Carnot cycle working between temperatures T₁ and T₂ (T₁ > T₂) is

(T₁ - T₂)/T₂
T₁/(T₁ - T₂)
T₂/(T₁ - T₂)
(T₁ - T₂)/T₁

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Chemical Engineering Thermodynamics
Which of the following is not a reversible process ?

Atmospheric pressure vaporisation of water at 100°C
Expansion of an ideal gas against constant pressure
None of these
Solution of NaCl in water at 50°C

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