Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = nR ln (V₂/V₁) + nCv ln (T₂/T₁) is valid for

Heating of a substance
Cooling of a substance
Reversible isothermal volume change
Simultaneous heating and expansion of an ideal gas

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Chemical Engineering Thermodynamics
The adiabatic throttling process of a perfect gas is one of constant enthalpy

Which is exemplified by a non-steady flow expansion
In which there is an increase in temperature
In which there is a temperature drop
Which can be performed in a pipe with a constriction

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Chemical Engineering Thermodynamics
Law of corresponding states says that

The surface of separation (i. e. the meniscus) between liquid and vapour phase disappears at the critical temperature
, two different gases behave similarly, if their reduced properties (i.e. P, V and T) are same
No gas can be liquified above the critical temperature, howsoever high the pressure may be
The molar heat of energy of gas at constant volume should be nearly constant (about 3 calories)

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