Chemical Engineering Thermodynamics
The necessary condition for phase equilibrium in a multiphase system of N components is that the

Sum of the chemical potentials of any given component in all the phases should be the same
Chemical potentials of all components should be same in a particular phase
None of these
Chemical potentials of a given component should be equal in all phases

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Chemical Engineering Thermodynamics
Gibbs-Duhem equation

Finds no application in gas-liquid equilibria involved in distillation
None of these
Applies only to binary systems
States that n₁dμ₁ + n₂dμ₂ + ....njdμj = 0, for a system of definite composition at constant temperature and pressure

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