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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
A chemical reaction will occur spontaneously at constant pressure and temperature, if the free energy is

Negative
Zero
None of these
Positive

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Chemical Engineering Thermodynamics
The fusion of a crystalline solid at its melting point to form a liquid at the same temperature is accompanied by

Decrease in enthalpy corresponding to evolution of heat
No change in enthalpy
Increase in enthalpy corresponding to absorption of heat
Decrease of entropy

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Chemical Engineering Thermodynamics
The root mean square speed of molecules of a gas is equal to (where, m = mass of the molecule K = Boltzman's constant, T = absolute temperature)

√(2KT/m)
√(3KT/m)
3KT/m
√(6KT/m)

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Chemical Engineering Thermodynamics
Which of the following is not a reversible process ?

None of these
Expansion of an ideal gas against constant pressure
Solution of NaCl in water at 50°C
Atmospheric pressure vaporisation of water at 100°C

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Chemical Engineering Thermodynamics
Fugacity is most helpful in

None of these
Representing actual behaviour of ideal gases
Representing actual behaviour of real gases
The study of chemical equilibria involving gases at atmospheric pressure

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Chemical Engineering Thermodynamics
In the equation, PVn = constant, if the value of n = 1, then it represents a reversible __________ process.

Adiabatic
Polytropic
Isobaric
Isothermal

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