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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
A gas has a volume of 27.3 c.c. at 0°C. Its volume at 10°C (if pressure remains unchanged) will be __________ c.c.

2.73
28.3
283
273

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Chemical Engineering Thermodynamics
A chemical reaction will occur spontaneously at constant pressure and temperature, if the free energy is

Negative
Positive
None of these
Zero

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂P)T = -(∂V/∂T)P
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂V)T = (∂P/∂T)V

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Chemical Engineering Thermodynamics
Entropy change for an irreversible isolated system is

> 0
< 0
∞

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Chemical Engineering Thermodynamics
With increase in temperature, the atomic heat capacities of all solid elements

Increases
Decreases
Remains unchanged
Decreases linearly

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Chemical Engineering Thermodynamics
When dilute aqueous solutions of two salts are mixed, the process is associated with

Change in temperature which is a function of composition
Decrease in temperature
No change in temperature
Increase in temperature

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