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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
In any spontaneous process, the __________ free energy decreases.

Gibbs
Both of the listed here
Neither A nor B
Helmholtz

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Chemical Engineering Thermodynamics
The Carnot co-efficient of performance (COP) of a domestic air conditioner compared to a household refrigerator is

Dependent on climatic conditions
Less
More
Same

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Chemical Engineering Thermodynamics
For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm³ and that in vapour phase in 391.1 cm³.Fugacity of water (in kPa) at 9000 kPa will be

6753.5
7058.3
9000
6738.9

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂S/∂V)T = (∂P/∂T)V
(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂P)T = -(∂V/∂T)P
(∂V/∂S)P = (∂T/∂P)S

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Chemical Engineering Thermodynamics
In an irreversible process

DE - dW - Tds = 0
Tds - dT + dW< 0
Tds = dE - dW = 0
Tds - dE + dW< 0

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Chemical Engineering Thermodynamics
With increase in temperature, the atomic heat capacities of all solid elements

Decreases linearly
Decreases
Remains unchanged
Increases

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