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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Trouton's ratio is given by (where λb, = molal heat of vaporisation of a substance at its normal boiling point, kcal/kmol Tb = normal boiling point, °K )

λb/Tb
√(λb/Tb)
Tb/λb
√(Tb/λb)

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Chemical Engineering Thermodynamics
The change in __________ is equal to the reversible work for compression in steady state flow process under isothermal condition.

Helmholtz free energy
Internal energy
Enthalpy
Gibbs free energy

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Chemical Engineering Thermodynamics
The chemical potential for a pure substance is __________ its partial molal free energy.

Equal to
Less than
More than
Not related to

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Chemical Engineering Thermodynamics
At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is

1.572
4.238
1.9398
3.389

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Chemical Engineering Thermodynamics
First law of thermodynamics deals with the

Reversible processes only
None of these
Direction of energy transfer
Irreversible processes only

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Chemical Engineering Thermodynamics
Cp of a gas at its critical temperature and pressure

Equals 0.24 kcal/kmol °K
Equals 1 kcal/kmol °K
Becomes infinity
Becomes zero

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