Chemical Engineering Thermodynamics
Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇋ PCl3 + Cl₂.Degree of dissociation of PCl5 will

None of these
Decrease on addition of Cl₂
Increase on addition of an inert gas at constant pressure
Decrease on increasing the pressure of the system

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Chemical Engineering Thermodynamics
The second law of thermodynamics states that

The total energy of system and surrounding remains the same
The energy change of a system undergoing any reversible process is zero
It is not possible to transfer heat from a lower temperature to a higher temperature
None of these

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Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

Volume in the liquid state is negligible compared with that in the vapour state
Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
All of these
Vapour pressure is relatively low and the temperature does not vary over wide limits

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