Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

Volume in the liquid state is negligible compared with that in the vapour state
Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
All of these
Vapour pressure is relatively low and the temperature does not vary over wide limits

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Chemical Engineering Thermodynamics
The third law of thermodynamics states that the

Heat capacity of a crystalline solid is zero at absolute zero temperature
Gases having same reduced properties behave similarly
None of these
Heat transfer from low temperature to high temperature source is not possible without external work

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