Chemical Engineering Thermodynamics
A refrigeration cycle is a reversed heat engine. Which of the following has the maximum value of the co-efficient of performance (COP) for a given refrigeration effect?

Vapor compression cycle using expansion engine
Vapor compression cycle using expansion valve
Carnot refrigeration cycle
Air refrigeration cycle

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Chemical Engineering Thermodynamics
Gibbs-Duhem equation

States that n₁dμ₁ + n₂dμ₂ + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
Applies only to binary systems
None of these
Finds no application in gas-liquid equilibria involved in distillation

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