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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Helmholtz free energy (A) is defined as

A = H - TS
A = E - TS
None of these
A = H + TS

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Chemical Engineering Thermodynamics
The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x₁. x₂, where A is a constant. The corresponding equation for ln y₁, where y₁ is the activity co-efficient of component 1, is

Ax₂
Ax₁
A . x₂²
Ax₁²

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Chemical Engineering Thermodynamics
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is

More in vapour phase
More in liquid phase
Same in both the phases
Replaced by chemical potential which is more in vapour phase

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Chemical Engineering Thermodynamics
A refrigerator works on the principle of __________ law of thermodynamics.

Third
Zeroth
First
Second

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Chemical Engineering Thermodynamics
Degree of freedom of a system consisting of a gaseous mixture of H₂ and NH₃ will be

3
2
0
1

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Chemical Engineering Thermodynamics
For organic compounds, group contribution method can be used for the estimation of

Specific volume
Thermal conductivity
Critical properties
Specific gravity

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