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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

-RT ln 0.5
2 RT
-2 RT ln 0.5
0.5 RT

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Chemical Engineering Thermodynamics
The principle applied in liquefaction of gases is

Joule-Thomson effect
Neither A nor B
Both A and B
Adiabatic expansion

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Chemical Engineering Thermodynamics
Helmholtz free energy (A) is defined as

A = H - TS
None of these
A = E - TS
A = H + TS

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Chemical Engineering Thermodynamics
For an ideal liquid solution, which of the following is unity?

Activity
Fugacity
Fugacity co-efficient
Activity co-efficient

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Chemical Engineering Thermodynamics
For an incompressible fluid, the __________ is a function of both pressure as well as temperature.

Internal energy
Entropy
Enthalpy
All of these

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Chemical Engineering Thermodynamics
If the molar heat capacities (Cp or Cv) of the reactants and products of a chemical reaction are identical, then, with the increase in temperature, the heat of reaction will

Decrease
Increase or decrease ; depends on the particular reaction
Increase
Remain unaltered

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