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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

-2 RT ln 0.5
0.5 RT
-RT ln 0.5
2 RT

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Chemical Engineering Thermodynamics
Which of the following is not a common refrigerant?

Carbon dioxide
Ammonia
Freon-12
Ethylene

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Chemical Engineering Thermodynamics
Heat requirement for decomposition of a compound into its elements is __________ that is evolved during the formation of that compound from its elements.

Different than
Less than
Greater than
The same

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Chemical Engineering Thermodynamics
In polytropic process (PVn = constant), if n = 1; it means a/an __________ process.

None of these
Isothermal
Reversible
Adiabatic

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Chemical Engineering Thermodynamics
The quantitative effect of temperature on chemical equilibrium is given by the

Arhenius equation
Vant-Hoff equation
Le-Chatelier's principle
None of these

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Chemical Engineering Thermodynamics
For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm³ and that in vapour phase in 391.1 cm³.Fugacity of water (in kPa) at 9000 kPa will be

7058.3
9000
6738.9
6753.5

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