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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

0.5 RT
-RT ln 0.5
2 RT
-2 RT ln 0.5

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Chemical Engineering Thermodynamics
Throttling process is a/an __________ process.

Reversible and constant entropy
Reversible and isothermal
Irreversible and constant enthalpy
Reversible and constant enthalpy

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Chemical Engineering Thermodynamics
The accentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr⁻¹ = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of accentric factor is always

> 1
< 1
> 2
< 3

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Chemical Engineering Thermodynamics
__________ calorimeter is normally used for measuring the dryness fraction of steam, when it is very low.

Separating
A combination of separating & throttling
Throttling
Bucket

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Chemical Engineering Thermodynamics
In a reversible process

DE - dW = Tds
DW - dE = Tds
Tds = dE + dW
Tds - dW + dE >0

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Chemical Engineering Thermodynamics
When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change. This is called the

Law of corresponding state
Le-Chatelier principle
Kopp's rule
Arrehenius hypothesis

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