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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

0.5 RT
2 RT
-2 RT ln 0.5
-RT ln 0.5

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Chemical Engineering Thermodynamics
Near their critical temperatures, all gases occupy volumes __________ that of the ideal gas.

More than
Half
Same as
Less than

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Chemical Engineering Thermodynamics
Van Laar equation deals with the activity co-efficients in

Ternary solutions
None of these
Azeotropic mixture only
Binary solutions

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Chemical Engineering Thermodynamics
The value of gas constant 'R' is

1.987 BTU/lb. mole °R
1.987 cal/gm mole °K
Both A and B
Neither A nor B

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Chemical Engineering Thermodynamics
A chemical reaction will occur spontaneously at constant pressure and temperature, if the free energy is

Positive
Negative
Zero
None of these

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Chemical Engineering Thermodynamics
For a spontaneous process, free energy

Is zero
Increases
Decreases whereas the entropy increases
And entropy both decrease

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