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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

-2 RT ln 0.5
2 RT
-RT ln 0.5
0.5 RT

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Chemical Engineering Thermodynamics
The co-efficient of performance (COP) of a refrigerating system, which is its index of performance, is defined as the ratio of useful refrigeration to the net work. The units of __________ and COP are the same.

Kinematic viscosity
Temperature
None of these
Work

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Chemical Engineering Thermodynamics
Internal energy of an ideal gas

Is independent of temperature
None of these
Increases with increase in pressure
Decreases with increase in temperature

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Chemical Engineering Thermodynamics
Generation of heat by friction is an example of a/an __________ change.

Isothermal
Reversible
Irreversible
Adiabatic

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Chemical Engineering Thermodynamics
What is the degree of freedom for two mis-cible (non-reacting) substances in vapor-liquid equilibrium forming an azeotrope?

1
2
3

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Chemical Engineering Thermodynamics
Which of the following has the least thermal efficiency?

Diesel engine
Steam engine
Carnot engine
Otto engine

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