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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For spontaneous changes in an isolated system (S = entropy)

Ds > 0
Ds = 0
Ds = Constant
Ds <0

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂V/∂S)P = (∂T/∂P)S
(∂S/∂P)T = -(∂V/∂T)P
(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂V)T = (∂P/∂T)V

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Chemical Engineering Thermodynamics
Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be

Same
Doubled
One fourth of its original value
Halved

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Chemical Engineering Thermodynamics
In the equation, PVn = constant, if the value of n = ± ∞, then it represents a reversible __________ process.

Isometric
Isothermal
Adiabatic
Isentropic

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Chemical Engineering Thermodynamics
Pick out the undesirable property for a good refrigerant.

Low freezing point
High viscosity
High thermal conductivity
Large latent heat of vaporisation

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Chemical Engineering Thermodynamics
The first law of thermodynamics is a statement of conservation of

Energy
Heat
Work
Momentum

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MORE MCQ ON Chemical Engineering Thermodynamics

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