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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is

Negative
Infinity
One
Zero

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Chemical Engineering Thermodynamics
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is

Replaced by chemical potential which is more in vapour phase
More in liquid phase
More in vapour phase
Same in both the phases

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Chemical Engineering Thermodynamics
Partial molal quantities are important in the study of

Ideal solutions
A pure component
Non-ideal mixtures
Ideal gases

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Chemical Engineering Thermodynamics
The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x₁. x₂, where A is a constant. The corresponding equation for ln y₁, where y₁ is the activity co-efficient of component 1, is

A . x₂²
Ax₁
Ax₁²
Ax₂

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Chemical Engineering Thermodynamics
Joule-Thomson experiment is

Isenthalpic
Both B & C
Adiabatic
Isobaric

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Chemical Engineering Thermodynamics
Third law of thermodynamics is concerned with the

Direction of energy transfer
Value of absolute entropy
None of these
Energy transfer

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