Chemical Engineering Thermodynamics
At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is

1.9398
1.572
4.238
3.389

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Chemical Engineering Thermodynamics
The necessary and sufficient condition for equilibrium between two phases is

The chemical potential of each component should be same in the two phases
The temperature of each phase should be same
The pressure should be same in the two phases
The concentration of each component should be same in the two phases

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