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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Free energy change at equilibrium is

Zero
Positive
Negative
Indeterminate

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Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

Tds = dE - PdV
DQ = CpdT + Vdp
DQ = CvdT + PdV
DE = Tds - PdV

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Chemical Engineering Thermodynamics
Internal energy of an ideal gas

Is independent of temperature
Decreases with increase in temperature
None of these
Increases with increase in pressure

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Chemical Engineering Thermodynamics
The equation relating E, P, V and T which is true for all substanes under all conditions is given by (∂E/∂V)T = T.(∂P/∂T)H - P . This equation is called the

Equation of state
Redlich-Kwong equation of state
Maxwell
Thermodynamic equation of state

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Chemical Engineering Thermodynamics
The rate at which a substance reacts is proportional to its active mass and the rate of a chemical reaction is proportional to the product of active masses of the reacting substances. This is the

Le-Chatelier's principle
None of these
Lewis-Randall rule
Statement of Vant-Hoff equation

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Chemical Engineering Thermodynamics
During adiabatic expansion of gas

Pressure remains constant
Pressure is increased
None of these
Temperature remains constant

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