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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Free energy change at equilibrium is

Negative
Positive
Zero
Indeterminate

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Chemical Engineering Thermodynamics
The free energy change for a chemical reaction is given by (where, K = equilibrium constant)

-R lnK
-RT lnK
T lnK
RT lnK

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Chemical Engineering Thermodynamics
Van Laar equation deals with the activity co-efficients in

Ternary solutions
Azeotropic mixture only
Binary solutions
None of these

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Chemical Engineering Thermodynamics
For a constant volume process

dQ = dE + pdV
dE = CpdT
dE = CvdT
dW = pdV

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Chemical Engineering Thermodynamics
The reaction A (l) R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The number of degrees of freedom are

3
1
2

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Chemical Engineering Thermodynamics
Entropy change of the reaction, H₂O(liquid) H₂O(gas), is termed as the enthalpy of

Formation
Formation
Vaporisation
Solution

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