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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The value of Joule-Thomson co-efficient, in case where cooling occurs after the throttling process is

∞
-ve
+ve

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Chemical Engineering Thermodynamics
At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)

μ° + RT ln f
μ° + R/T lnf
μ° + T lnf
μ°+ R lnf

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Chemical Engineering Thermodynamics
Pressure-enthalpy chart is useful in refrigeration. The change in internal energy of an ideal fluid used in ideal refrigeration cycle is

Infinity
Negative
Zero
Positive

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Chemical Engineering Thermodynamics
First law of thermodynamics deals with the

Irreversible processes only
Reversible processes only
None of these
Direction of energy transfer

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Chemical Engineering Thermodynamics
For an ideal solution, the value of activity co-efficient is

> 1
1
< 1

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Chemical Engineering Thermodynamics
For organic compounds, group contribution method can be used for the estimation of

Specific gravity
Specific volume
Thermal conductivity
Critical properties

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