Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature and pressure only
Temperature, pressure, liquid composition xi and vapour composition yi
Temperature only
Temperature, pressure and liquid composition xi only

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Chemical Engineering Thermodynamics
Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇋ PCl3 + Cl₂.Degree of dissociation of PCl5 will

Decrease on increasing the pressure of the system
Increase on addition of an inert gas at constant pressure
Decrease on addition of Cl₂
None of these

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