Structure and Properties of Peptides
The peptide, Val-Lys-Glu-Met-Ser-Trp-Arg-Ala, was digested with cyanogen bromide (CNBr) to produce:

Val-Lys-Glu + Met-Ser-Trp-Arg-Ala
Val-Lys-Glu-Met-Ser-Trp + Arg-Ala
Val-Lys-Glu-Met + Ser-Trp-Arg-Ala
Val-Lys + Glu-Met-Ser + Trp-Arg-Ala

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Structure and Properties of Peptides
The Ramachandran Plot illustrates the fact that

the F & Y angles can assume only a single value in a protein
the F & Y angles can assume any value in a peptide
the peptide bond is planar
the F & Y angles can assume approximately three different values

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Structure and Properties of Peptides
In deoxy hemoglobin (Hb), the Fe (II) is coordinated to

two nitrogens of heme and to three His residues in Hb
four nitrogens of heme, the proximal His, and a water molecule
two nitrogens of heme and to three water molecules
four nitrogens of heme and to a water molecule

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