Chemical Engineering Thermodynamics
The equation DU = Tds - PdV is applicable to infinitesimal changes occuring in

An open system of constant composition
An open system with changes in composition
A closed system with changes in composition
A closed system of constant composition

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Chemical Engineering Thermodynamics
An irreversible process

Is an idealised visualisation of behaviour of a system
Is the analog of linear frictionless motion in machines
Yields the maximum amount of work
Yields an amount of work less than that of a reversible process

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