Chemical Engineering Thermodynamics
The equation DU = Tds - PdV is applicable to infinitesimal changes occuring in

An open system of constant composition
A closed system of constant composition
A closed system with changes in composition
An open system with changes in composition

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Chemical Engineering Thermodynamics
In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants )

Addition of inert gas favours the forward reaction, when Δx is positive
Pressure has no effect on equilibrium, when Δn = 0
All of these
Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero)

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Chemical Engineering Thermodynamics
A large iceberg melts at the base, but not at the top, because of the reason that

The iceberg remains in a warmer condition at the base
All of these
Ice at the base contains impurities which lowers its melting point
Due to the high pressure at the base, its melting point reduces

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