Chemical Engineering Thermodynamics
Critical solution temperature (or the con-solute temperature) for partially miscible liquids (e.g., phenol-water) is the minimum temperature at which

A homogeneous solution (say of phenol water) is formed
Mutual solubility of the two liquids shows a decreasing trend
None of these
Two liquids are completely separated into two layers

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Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature and pressure only
Temperature only
Temperature, pressure and liquid composition xi only
Temperature, pressure, liquid composition xi and vapour composition yi

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