Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature only
Temperature and pressure only
Temperature, pressure, liquid composition xi and vapour composition yi
Temperature, pressure and liquid composition xi only

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Chemical Engineering Thermodynamics
The adiabatic throttling process of a perfect gas is one of constant enthalpy

In which there is an increase in temperature
Which is exemplified by a non-steady flow expansion
In which there is a temperature drop
Which can be performed in a pipe with a constriction

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