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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Absorption/evolution of heat during conversion of a substance from one allotropic form to another is termed as the heat of

Vaporisation
Fusion
Transition
Sublimation

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Chemical Engineering Thermodynamics
Lowering of condenser temperature (keeping the evaporator temperature constant) in case of vapour compression refrigeration system results in

Decreased COP
Increased COP
Increased or decreased COP ; depending upon the type of refrigerant
Same COP

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Chemical Engineering Thermodynamics
Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be

One fourth of its original value
Doubled
Halved
Same

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Chemical Engineering Thermodynamics
In the ammonia synthesis reaction, N₂ + 3H₂ ⇋ 2NH₃ + 22.4 kcal, the formation of NH₃ will be favoured by

High temperature
Low pressure
Low temperature only
Both low temperature and high pressure

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Chemical Engineering Thermodynamics
Trouton's ratio is given by (where λb, = molal heat of vaporisation of a substance at its normal boiling point, kcal/kmol Tb = normal boiling point, °K )

λb/Tb
√(λb/Tb)
Tb/λb
√(Tb/λb)

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Chemical Engineering Thermodynamics
The accentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr⁻¹ = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of accentric factor is always

> 1
< 3
> 2
< 1

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