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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Absorption/evolution of heat during conversion of a substance from one allotropic form to another is termed as the heat of

Vaporisation
Fusion
Sublimation
Transition

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Chemical Engineering Thermodynamics
Lowering of condenser temperature (keeping the evaporator temperature constant) in case of vapour compression refrigeration system results in

Increased or decreased COP ; depending upon the type of refrigerant
Same COP
Decreased COP
Increased COP

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Chemical Engineering Thermodynamics
The energy of activation of exothermic reaction is

Very large compared to that for en-dothermic reaction
Negative
Zero
Not possible to predict

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Chemical Engineering Thermodynamics
Boyle's law for gases states that

P ∝ 1/V, when temperature & mass of the gas remain constant
P/V = constant, for any gas
P ∝ 1/V, when temperature is constant
P ∝ V, at constant temperature & mass of the gas

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Chemical Engineering Thermodynamics
Fugacity and pressure are numerically not equal for the gases

At low temperature and high pressure
Both A and B
At standard state
In ideal state

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Chemical Engineering Thermodynamics
If the molar heat capacities (Cp or Cv) of the reactants and products of a chemical reaction are identical, then, with the increase in temperature, the heat of reaction will

Remain unaltered
Increase or decrease ; depends on the particular reaction
Decrease
Increase

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