Mass Transfer
Entrainer used in azeotropic distillation should

Have high latent heat of vaporisation
Form a new azeotrope of low relative volatility with one of the constituents of the mixture
Form a low boiling azeotrope with one of the constituents of the mixture
Have high viscosity to provide high tray efficiency

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Mass Transfer
In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because

Saturated steam is used for steam distillation
Total pressure is less
Mixing of steam with the material being vaporised is not so intimate as to result in equilibrium condition
Temperature is less

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