Mass Transfer
Chemisorption (chemical adsorption) is

Same as "Van der Waals" adsorption
An irreversible phenomenon
Characterised by adsorption of heat
A reversible phenomenon

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Mass Transfer
To get high tray efficiency

Interfacial surface between liquid and gas phase should be large
Time of contact between the two phases should be less
Liquid entrainment should be severe
Gas velocity should be very low

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Mass Transfer
Henry's law states that the

Partial pressure is equal to the product of the mole fraction and total pressure
Partial pressure of a component over a solution is proportional to the mole fraction in the vapour
Vapour pressure is equal to the product of the mole fraction and total pressure
Partial pressure of a component over a solution is proportional to its mole fraction in the liquid

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Mass Transfer
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when

Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law
Only liquid phase obeys Dalton's law
Only vapor phase follows Raoult's law
Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

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