Chemical Engineering Thermodynamics
On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)S and the slope of the reversible isothermal line (∂P/∂V)T are related as (where, y = Cp/Cv) )

(∂P/∂V)S = (∂P/∂V)T
(∂P/∂V)S = y(∂P/∂V)T
(∂P/∂V)S = 1/y(∂P/∂V)T
(∂P/∂V)S = [(∂P/∂V)T]Y

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Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

Volume in the liquid state is negligible compared with that in the vapour state
Vapour pressure is relatively low and the temperature does not vary over wide limits
Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
All of these

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Chemical Engineering Thermodynamics
An irreversible process

Is the analog of linear frictionless motion in machines
Yields an amount of work less than that of a reversible process
Yields the maximum amount of work
Is an idealised visualisation of behaviour of a system

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