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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The melting point of paraffin wax (which contracts on solidification) __________ with pressure rise.

Decreases
Remains unchanged
Decreases linearly
Increases

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Chemical Engineering Thermodynamics
In any spontaneous process,

Both F and A decreases
Only A decreases
Both F and A increase
Only F decreases

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Chemical Engineering Thermodynamics
Compressibility factor (i.e., the ratio of actual volume of gas to the volume predicted by ideal gas law) for all gases are

Both B & C
Same at the same reduced temperature
Always greater than one
Same at the same reduced pressure

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Chemical Engineering Thermodynamics
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is

Replaced by chemical potential which is more in vapour phase
More in vapour phase
Same in both the phases
More in liquid phase

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Chemical Engineering Thermodynamics
The freezing point of a liquid decreases when the pressure is increased, if the liquid __________ while freezing.

Expands
Contracts
Does not change in volume
Either A, B or C

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Chemical Engineering Thermodynamics
In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is

Unpredictable; depends on the particular reaction
More
Less
Same

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