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Chemical Reaction Engineering

Chemical Reaction Engineering
If CA is the quantity of reactants initially present, the quantity left after 'n' half periods will be equal to

(CA)1/2n
(1/2)n.CA
(CA)n
(CA)1/n

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Chemical Reaction Engineering
In the hydrodealkylation of toluene to benzene, the following reactions occur:C₇H₈ + H₂ → C₆H₆ + CH₄2C₆H₆ ⇋ C₁₂H₁₀ + H₂Toluene and hydrogen are fed to a reactor in a molar ratio 1:5.80% of the toluene gets converted and the selectivity of benzene(defined as moles of benzene formed/moles of toluene converted) is 90%. The fractional conversion of hydrogen is

0.152
0.144
0.136
0.16

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Chemical Reaction Engineering
With the same reaction time, initial concentration and feed rate, the reaction 2A → B is carried out separately in CSTR and P.F. reactor of equal volumes. The conversion will be

Higher in P.F. reactor
Higher in CSTR
Same in both the reactors
Data insufficient; can't be predicted

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Chemical Reaction Engineering
The performance of a cascade of CSTR's can be improved by adding

A P.F. reactor in parallel
More CSTR's in parallel
A P.F. reactor in series
More CSTR's in series

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Chemical Reaction Engineering
At a given temperature, K₁, K₂ and K3 are equilibrium constants for the following reactions 1, 2, 3 respectively. CH₄(g) + H₂O(g) ⇋ CO(g) + 3H₂(g), CO(g) + H₂O(g) ⇋ CO₂(g) + H₂(g) CH₄(g) + 2H₂O(g) ⇋ CO₂(g) + 4H₂(g) Then K₁, K₂ and K3 are related as:

K3 = (K₁.K₂)0.5
K3 = (K₁.K₂)2
K3(K₁+K₂)/2
K3 = K₁.K₂

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Chemical Reaction Engineering
Molecularity of a reaction

Is always equal to the overall order of reaction
May not be equal to the order of reaction
Both B and C
Can

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