Chemical Reaction Engineering
In solid catalysed reactions the diffusional effects are more likely to affect the overall rate of reaction for

Fast reaction in catalyst of large pore diameter
Fast reactions in catalyst of small pore diameter
Slow reactions in catalyst of small pore diameter
Slow reactions in catalyst of large pore diameter

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Chemical Reaction Engineering
For a first order isothermal chemical reaction in a porous catalyst, the effectiveness factor is 0.3. The effectiveness factor will increase if the

Catalyst size is increased or the catalyst diffusivity is reduced
Catalyst size is reduced or the catalyst diffusivity is increased
Catalyst size is increased or the catalyst diffusivity is increased
Catalyst size is reduced or the catalyst diffusivity is reduced

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