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Chemical Reaction Engineering

Chemical Reaction Engineering
From Arhenius law, a plot of loge K versus 1/T gives a straight line with a slope of (-E/R). The unit of E/R is

K cal
°K
K cal. °K
K cal/°K

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Chemical Reaction Engineering
The half life period of a first order reaction is

Dependent on initial concentration of the reactants
Always the same irrespective of the reaction
Half the specific rate constant
Proportional to the initial concentration of reactants

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Chemical Reaction Engineering
If the pore diffusion controls in a catalytic reaction, the apparent activation energy Ea is equal to

The intrinsic activation energy E
(E + ED)/2
(E + ED) where ED is activation due to diffusion
ED/2

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Chemical Reaction Engineering
Catalyst is a substance, which __________ chemical reaction.

Increases the speed of a
Can either increase or decrease the speed of a
Alters the value of equilibrium constant in a reversible
Decreases the speed of a

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Chemical Reaction Engineering
Transition state theory relates the above quantities as

K ∝ e-E/RT
K ∝ T.eE/RT
K ∝ T1.5
K ∝ √T

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Chemical Reaction Engineering
If the time required for half change is inversely proportional to the square of initial concentration and the velocity depends on the units in which the concentration term is expressed, then the order of reaction is

2
1
0
3

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