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Chemical Reaction Engineering

Chemical Reaction Engineering
From Arhenius law, a plot of loge K versus 1/T gives a straight line with a slope of (-E/R). The unit of E/R is

K cal/°K
K cal. °K
K cal
°K

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Chemical Reaction Engineering
The half life period of a first order reaction is

Half the specific rate constant
Dependent on initial concentration of the reactants
Always the same irrespective of the reaction
Proportional to the initial concentration of reactants

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Chemical Reaction Engineering
The effectiveness factor for large value of Thiele modulus (L√(K/D1)) of a solid catalysed first order reaction is equal to (where, L = length of the reactor, cm, D1 = diffusion co-efficient, cm²/second)

1/(L√(K/D1))
L√(K/D1)
∞
1

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Chemical Reaction Engineering
An irreversible first order reaction is being carried out in a CSTR and PFR of same volume. The liquid flow rates are same. The relative conversion will

Depend on the temperature
Be same in both cases
Be more in CSTR than in PFR
Be more in PFR than in CSTR

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Chemical Reaction Engineering
For an ideal mixed flow reactor (CSTR), the exit age distribution E(t) is given by

A ramp function
None of these
A step function
A dirac delta function

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Chemical Reaction Engineering
A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and kg respectively. The effective rate constant (keff) is given by

keff = (kkg)1/2
1/keff = 1/k + 1/kg
keff = k + kg
keff = (k+ kg)/2

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