Chemical Reaction Engineering
Brunaur, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation?

The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process
Langmuir
There is no dynamic equilibrium between successive layer
None of these

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Chemical Reaction Engineering
For all positive reaction orders for a particular duty,

Mixed reactor is always larger than the plug-flow reactor
Reactor size is independent of the type of flow
Ratio of the volume of the mixed reactor to that of the plug-flow reactor decreases with order
Density variation during reaction affects design

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