Structure and Properties of Peptides
Hydrogen bonds in a-helices are

analogous to the steps in a spiral staircase
more numerous than Vander Waals interactions
not present at Phe residues
roughly parallel to the helix axis

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Structure and Properties of Peptides
In deoxy hemoglobin (Hb), the Fe (II) is coordinated to

four nitrogens of heme and to a water molecule
two nitrogens of heme and to three water molecules
four nitrogens of heme, the proximal His, and a water molecule
two nitrogens of heme and to three His residues in Hb

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